가능한것 같습니다. 인터넷에는 이렇게 나와 있네요.
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"probation" is something that exists only in private contract law, and isn't recognized formally as being part of provincial or federal labour legislation.

As such, as long as you have the required number of hours worked for EI, you should be eligible.
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참고만 하시고 자세한건 Labour Lawyer나 노무사 또는 ESDC (Employment and Social Development Canada)에 문의해 보세요.